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Metabolic reasoning

Whole-map thinking. Each case is a chain of cause → effect that ends in the labs: why DKA has ketones and hyperglycemia, why a drinker goes hypoglycemic, why an infant with MCAD deficiency spills no ketones. Walk through the chain on the map, then order it yourself, answer the why questions, or diagnose from the labs.

Case
The big map. Highlighted boxes are the parts of metabolism the current step is about. Scroll sideways when zoomed.
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GlycogenGlycogenGlucoseGlucoseGalactoseGalactoseFructoseFructoseGlucose-6-phosphateGlucose-6-phosphateRibose-5-P + NADPHRibose-5-P + NADPHFructose-6-phosphateFructose-6-phosphateFructose-1,6-bisPFructose-1,6-bisPG3P / DHAPG3P / DHAPGlycerol (fat)Glycerol (fat)PhosphoenolpyruvatePhosphoenolpyruvatePyruvatePyruvateLactateLactateAlanine (amino acids)Alanine (amino acids)Acetyl-CoAAcetyl-CoAOxaloacetateOxaloacetateCitrateCitrateTCA cycle → NADH/FADH₂TCA cycle → NADH/FADH₂ETC → ATPETC → ATPFatty acidsFatty acidsTriacylglycerolTriacylglycerolKetone bodiesKetone bodiesCholesterolCholesterolEthanolEthanolGlycogenolysis (phosphorylase)Hexokinase / glucokinaseLeloir pathway (GALT)HMP shunt (G6PD)GlycolysisPFK-1 ★ / FBPase-1AldolaseFructokinase → aldolase B(bypasses PFK-1)Glycerol kinase (liver)Hormone-sensitive lipaseLower glycolysis (2 ATP, 2 NADH)Pyruvate kinaseALT (glucose-alanine cycle)LDH (anaerobic)PDH (irreversible; thiamine)ADH → ALDH (2 NADH)Pyruvate carboxylase (biotin; +acetyl-CoA)Citrate synthaseCitrate synthaseTCA cycleOXPHOSATP-citrate lyase → ACC → FAS(needs NADPH)Hormone-sensitive lipaseHMG-CoA synthase / lyase (liver)HMG-CoA reductase (cytosol)

A teenager breathing fast and deep

Maya, 14, is brought in by her mother with 2 days of nausea, vomiting and diffuse abdominal pain, and 1 week of thirst, urination and weight loss. She is confused, breathing fast and deep (RR 32), HR 118, BP 98/60, afebrile. Her breath smells sweet and fruity.

Glucose489 mg/dL
HCO₃⁻12 mEq/L
Anion gap24
pH7.22
pCO₂20 mmHg
β-Hydroxybutyrate8.3 mmol/L↑↑
Urine ketones4+
K⁺5.8 mEq/L
Na⁺128 mEq/L
Triglycerides519 mg/dL

Diabetic ketoacidosis (new type 1 diabetes)

One hormonal derangement — absolute insulin deficiency with unopposed glucagon — explains every value.

Condition card: Diabetic ketoacidosis (DKA) →Pathway map →

  1. Autoimmune destruction of β-cells → absolute insulin deficiency; glucagon is unopposed.

Pathways involved: Lipolysis, carnitine shuttle & β-oxidation, Ketogenesis & ketone body use, Gluconeogenesis, Glycolysis. Drill them one at a time in Metabolic pathways.

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