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Metabolic reasoning

Whole-map thinking. Each case is a chain of cause → effect that ends in the labs: why DKA has ketones and hyperglycemia, why a drinker goes hypoglycemic, why an infant with MCAD deficiency spills no ketones. Walk through the chain on the map, then order it yourself, answer the why questions, or diagnose from the labs.

Case
The big map. Highlighted boxes are the parts of metabolism the current step is about. Scroll sideways when zoomed.
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GlycogenGlycogenGlucoseGlucoseGalactoseGalactoseFructoseFructoseGlucose-6-phosphateGlucose-6-phosphateRibose-5-P + NADPHRibose-5-P + NADPHFructose-6-phosphateFructose-6-phosphateFructose-1,6-bisPFructose-1,6-bisPG3P / DHAPG3P / DHAPGlycerol (fat)Glycerol (fat)PhosphoenolpyruvatePhosphoenolpyruvatePyruvatePyruvateLactateLactateAlanine (amino acids)Alanine (amino acids)Acetyl-CoAAcetyl-CoAOxaloacetateOxaloacetateCitrateCitrateTCA cycle → NADH/FADH₂TCA cycle → NADH/FADH₂ETC → ATPETC → ATPFatty acidsFatty acidsTriacylglycerolTriacylglycerolKetone bodiesKetone bodiesCholesterolCholesterolEthanolEthanolGlycogenolysis (phosphorylase)Hexokinase / glucokinaseLeloir pathway (GALT)HMP shunt (G6PD)GlycolysisPFK-1 ★ / FBPase-1AldolaseFructokinase → aldolase B(bypasses PFK-1)Glycerol kinase (liver)Hormone-sensitive lipaseLower glycolysis (2 ATP, 2 NADH)Pyruvate kinaseALT (glucose-alanine cycle)LDH (anaerobic)PDH (irreversible; thiamine)ADH → ALDH (2 NADH)Pyruvate carboxylase (biotin; +acetyl-CoA)Citrate synthaseCitrate synthaseTCA cycleOXPHOSATP-citrate lyase → ACC → FAS(needs NADPH)Hormone-sensitive lipaseHMG-CoA synthase / lyase (liver)HMG-CoA reductase (cytosol)

Ketones without hyperglycemia

A 48-year-old chronic drinker with poor nutrition has been vomiting for 2 days after a binge and has not been able to keep alcohol or food down. He is tachypneic with abdominal pain.

Glucose84 mg/dLnormal
Anion gap22
HCO₃⁻14 mEq/L
β-Hydroxybutyrate↑↑↑↑
Urine ketones (nitroprusside)tracemisleadingly low
Ethanolundetectable

Alcoholic ketoacidosis

Starvation + a liver flooded with NADH: lipolysis and ketogenesis with normal or low glucose — no insulin required to treat.

Condition card: Alcoholic ketoacidosis (AKA) →Pathway map →

  1. Days of vomiting and no food → glycogen depleted, insulin low, glucagon/epinephrine high.

Pathways involved: Ethanol metabolism, Ketogenesis & ketone body use, Lipolysis, carnitine shuttle & β-oxidation. Drill them one at a time in Metabolic pathways.

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